Fiona Bruce and the team visit Dumfries House near Ayr in Scotland.
Objects intriguing the experts include an early toy train in remarkable condition, an outstanding example of Chippendale furniture, and a glass vase bought at a boot sale, which hides a stunning valuation.
There is also a special interview with HRH The Prince of Wales about his involvement in the rescue mission to save the unique collection at Dumfries House from being broken up.
